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2011- Present

60. Rungmai Limvorapitux, Lien-Yang Chou, Allison P. Young, Chia-Kuang Tsung*, and SonBinh T. Nguyen*, Coupling Molecular and Nanoparticle Catalysts on Single Metal–Organic Framework Microcrystals for the Tandem Reaction of H2O2 Generation and Selective Alkene Oxidation. ACS Cata. 2017, DOI: 10.1021/acscatal.6b03632

59. Lee, H. K.; Lee, Y. H.; Liu, Y.; Morabito, J. V.; Phang, I. Y.; Pedireddy, S.; Koh, C. S. L.; Han, X.; Chou, L.-Y.; Tsung, C.-K.*; Ling, X. Y.*, Driving CO2 to a Quasi-Condensed Phase at the Interface between a Nanoparticle Surface and a Metal-Organic Framework at 1 bar and 298 K. J. Am. Chem. Soc. 2017, 139, 11513.

58. Zhuang, J.; Young, A. P.; Tsung, C.-K.*, Integration of Biomolecules with Metal–Organic Frameworks. Small 2017, 13, 1700880.

57. Liao, F.; Lo, W.,  Hsu, Y.;  Wu, C.;  Wang, S. Shieh, F.; Morabito, J. V.; Chou, L.; Wu, C.; Tsung, C.-K.*, Shielding Against Unfolding by Embedding Enzymes in Metal-Organic Frameworks via a de novo Approach. J. Am. Chem. Soc. 2017, 139, 6530.

56. Giustra, Z. X.; Chou, L. Y.; Tsung, C.-K.*; Liu, S. Y.*, Kinetics of -CH2CH2- Hydrogen Release from a BN-cyclohexene Derivative. Organometallics 2016, 35, 2425.

55. Sneed, B. T.; Golden, M. C.; Liu, Y.; Lee, H. K.; Andoni, I.; Young, A. P.; McMahon, G.; Erdman, N.; Shibata, M.; Ling, X. Y.; Tsung, C.-K.*, Promotion of the halide effect in the formation of shaped metal nanocrystals via a hybrid cationic, polymeric stabilizer: Octahedra, cubes, and anisotropic growth. Surf. Sci.2016, 648, 307.

54. Sheehan, M. K.; Rudden, M.; Cai, H.; Tsung, C.-K.*, Carbon Coated Metal Nanoparticles for Electrocatalysis. Catal. Lett. 2016, 2, 309.

53. Chou, L.-Y.; Hu, P.; Zhuang, J.; Morabito, J. V.; Ng, K. C.; Kao, Y.-C.; Wang, S.-C.; Shieh, F.-K.; Kuo, C.-H.; Tsung, C.-K.*, Formation of hollow and mesoporous structures in single-crystalline microcrystals of metal-organic frameworks via double-solvent mediated overgrowth, Nanoscale 2015, 7, 19408.

52. Zhuang, J; Chou, L.; Sneed, B. T.; Cao, Y.; Hu, P.; Feng, L.; Tsung, C.-K.*, Surfactant-Mediated Conformal Overgrowth of Core-Shell Metal-Organic Framework Materials with Mismatched Topologies, Small 2015, 11, 5551.

51. Sneed, B. T.; Young, A. P.; Tsung, C.-K.*, Building up strain in colloidal metal nanoparticle catalysts, Nanoscale 2015, 7, 12248. [Article]

50. Scardi, P.; Leonardi, A.; Gelisio, L.; Suchomel, M. R.; Sneed, B. T.; Sheehan, M. K.; Tsung, C.-K., Anisotropic atom displacement in Pd nanocubes resolved by molecular dynamics simulations supported by x-ray diffraction imaging. Phys. Rev. B 2015, 91, 155414. [Article]

49. Fa-Kuen Shieh, Shao-Chun Wang, Chia-I Yen, Chang-Cheng Wu, Saikat Dutta, Lien-Yang Chou, Joseph V. Morabito, Pan Hu, Ming-Hua Hsu, Kevin C.-W. Wu, and Chia-Kuang Tsung*, Imparting Functionality to Biocatalysts via Embedding Enzymes into Nanoporous Materials by a de novo Approach: Size-Selective Sheltering of Catalase in Metal-Organic Framework Microcrystals.
J. Am. Chem. Soc.
2015, 137, 4276.

48. Pan Hu, Joseph V. Morabito, and Chia-Kuang Tsung, Core-shell catalysts of metal nanoparticle core and metal-organic-framework shell. ACS Catalysis 2014, 4, 4409. [Article]

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47. Dachao Hong, Yusuke Yamada, Margaret Sheehan, Shinya Shikano, Chun-Hong Kuo, Ming Tian, Chia-Kuang Tsung, and Shunichi Fukuzumi, Mesoporous Nickel Ferrites with Spinel Structure Prepared by an Aerosol-Spray-Pyrolysis Method for Photocatalytic Hydrogen Evolution. ACS Sustainable Chemistry & Engineering 2014, 2, 2588. [Article]


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46.  Casey N. Brodsky, Allison P. Young, Ka Chon Ng, Chun-Hong Kuo, and Chia-Kuang Tsung, Electrochemically Induced Surface Metal Migration in Well-Defined Core-Shell Nanoparticles and Its General Influence on Electrocatalytic Reactions. ACS Nano 2014, 8, 9368. [Article]



45.  Joseph V. Morabito, Lien-Yang Chou, Zhehui Li, Cesar M. Manna, Christopher A. Petroff, Rutvin Kyada, Joseph M. Palomba, Jeffery A. Byers, and Chia-Kuang Tsung, Molecular Encapsulation Beyond the Aperture Size Limit Through Dissociative Linker Exchange in Metal-Organic Framework Crystals. J. Am. Chem. Soc. 2014, 136, 12540. [Article]


44.  Pan Hu, Jia Zhuang, Lien-Yang Chou, Hiang Kwee Lee, Xing Yi Ling, Yu-Chun Chuang, and Chia-Kuang Tsung, Surfactant-Directed Atomic to Mesoscale Alignment: Metal Nano-crystals Encased Individually in Single-Crystalline Porous Nanostruc-tures. J. Am. Chem. Soc. 2014, 136, 10561. [Article]

43.  Brian T. Sneed, Allison P. Young, Daniel Jalalpoor, Matthew C. Golden, Shunjia Mao, Ying Jiang, Yong Wang, and Chia-Kuang Tsung, Shaped Pd–Ni–Pt Core-Sandwich-Shell Nanoparticles: Influence of Ni Sandwich Layers on Catalytic Electrooxidations. ACS Nano 2014, 8, 7239. [Article]

42. Jia Zhuang, Chun-Hong Kuo, Lien-Yang Chou, De-Yu Liu, Eranthie Weerapana, and Chia-Kuang Tsung, Optimized Metal-Organic Framework Nanospheres for Drug Delivery: Evaluation of Small-Molecule Encapsulation. ACS Nano. 2014, 8, 2812.  [Article]

41. Fa-Kuen Shieh, Chia-Teng Hsiao, Yu-Chein Sue, Kuan-Wei Lin, Chang-Cheng Wu, Xi-Hong Chen, Lei Wan, Ming-Hua Hsu, Jih Ru Hwu, Hsien-Ming Kao, Chia-Kuang Tsung, and Kevin C.-W. Wu, Size-Adjustable Annular Ring-Functionalized Mesoporous Silica as Effective and Selective Adsorbents for Heavy Metal Ions, RSC Adv. 2013, 3, 25686. [Article]

40. Sneed, B.T.; Brodsky, C.N.; Kuo, C.-H.; Lamontagne, L.K.; Jiang, Y.; Wang, Y.; Tao, F.; Huang, X.; Tsung, C.-K., Nanoscale-Phase-Separated Pd-Rh Boxes Synthesized via Metal Migration: An Archetype for Studying Lattice Strain and Composition Effects in Electrocatalysis. J. Am. Chem. Soc. 2013, 135, 14691. [Article]

39.  Kuo, C. H.; Lamontagne L. K.; Brodsky, C. N.; Chou, L. Y.; Zhuang, J.; Sneed, B. T.; Tsung, C.-K., The Effect of Lattice Strain on the Catalytic Properties of Pd Nanocrystals. ChemSusChem 2013, 6, 1993. [Article]

38.  Zhang, S.; Nguyen, L.; Zhu, Y.; Zhan, S.; Tsung, C.-K.; Tao, F., In-Situ Studies of Nanocatalysis. Accounts Chem. Res. 2013, 46, 1731. [Article]


37. Baldyga, L. M.; Blavo, S. O.; Kuo, C. H.; Tsung, C.-K.; Kuhn, J. N., Size-Dependent Sulfur Poisoning of Silica-Supported Monodisperse Pt Nanoparticle Hydrogenation Catalysts. ACS Catalysis 2012, 2, 2626. [Article]


36. Sneed, B. T.; Kuo, C. H.; Brodsky, C. N.; Tsung, C.-K., Iodide-Mediated Control of Rhodium Epitaxial Growth on Well-Defined Noble Metal Nanocrystals: Synthesis, Characterization, and Structure-Dependent Catalytic Properties. J. Am. Chem. Soc. 2012, 134, 18417. [Article]


35.  Kuo, C. H.; Tang, Y.; Chou, L. Y.; Sneed, B. T.; Brodsky, C. N.; Zhao, Z. P.; Tsung, C.-K., Yolk-Shell Nanocrystal@ZIF-8 Nanostructures for Gas-Phase Heterogeneous Catalysis with Selectivity Control. J. Am. Chem. Soc. 2012, 134, 14345. [Article]


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Chemical Processing: http://www.chemicalprocessing.com/articles/2013/porous-nanostructure-boosts-selectivity/

Science Daily: http://www.sciencedaily.com/releases/2012/12/121213085210.htm

RD Magazine Online: http://www.rdmag.com/news/2012/12/thin-skinned-catalyst-chemical-reactions

PhysOrg: http://phys.org/news/2012-12-thin-skinned-catalyst-chemical-reactions.html

Bio-Medicine http://www.bio-medicine.org/biology-technology-1/A-thin-skinned-catalyst-for-chemical-reactions-23784-1/


34.   Yamada, Y.; Tsung, C. -K.; Huang, W.; Huo, Z. Y.; Habas, S. E.; Soejima, T.; Aliaga, C. E.; Somorjai, G. A.; Yang, P. D., Nanocrystal bilayer for tandem catalysis. Nat. Chem. 2011, 3, 372.

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33.  Huang, Y.; Shi, Q. H.; Tsung, C. -K.; Gunawardena, H. P.; Xie, L.; Yu, Y. B.; Liang, H. J.; Yang, P. Y.; Stucky, G. D.; Chen, X. A., An optimized magnetite microparticle-based phosphopeptide enrichment strategy for identifying multiple phosphorylation sites in an immunoprecipitated protein. Anal. Biochem. 2011, 409, 301.



32.  Feng, L.; Hoang, D. T.; Tsung, C. -K.; Huang, W. Y.; Lo, S. H. Y.; Wood, J. B.; Wang, H. T.; Tang, J. Y.; Yang, P. D., Catalytic Properties of Pt Cluster-Decorated CeO2 Nanostructures. Nano Res. 2011, 4, 61.


31.  Aliaga, C.; Tsung, C. -K.; Alayoglu, S.; Komvopoulos, K.; Yang, P. D.; Somorjai, G. A., Sum Frequency Generation Vibrational Spectroscopy and Kinetic Study of 2-Methylfuran and 2,5-Dimethylfuran Hydrogenation over 7 nm Platinum Cubic Nanoparticles. J. Phys. Chem. C 2011, 115, 8104.

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30.  Witham, C. A.; Huang, W. Y.; Tsung, C. -K.; Kuhn, J. N.; Somorjai, G. A.; Toste, F. D., Converting homogeneous to heterogeneous in electrophilic catalysis using monodisperse metal nanoparticles. Nat. Chem. 2010, 2 (1), 36.

29.  Tao, F.; Grass, M. E.; Zhang, Y. W.; Butcher, D. R.; Aksoy, F.; Aloni, S.; Altoe, V.; Alayoglu, S.; Renzas, J. R.; Tsung, C. -K.; Zhu, Z. W.; Liu, Z.; Salmeron, M.; Somorjai, G. A., Evolution of Structure and Chemistry of Bimetallic Nanoparticle Catalysts under Reaction Conditions. J. Am. Chem. Soc. 2010, 132 (25), 8697.

28.  Kliewer, C. J.; Aliaga, C.; Bieri, M.; Huang, W. Y.; Tsung, C. -K.; Wood, J. B.; Komvopoulos, K.; Somorjai, G. A., Furan Hydrogenation over Pt(111) and Pt(100) Single-Crystal Surfaces and Pt Nanoparticles from 1 to 7 nm: A Kinetic and Sum Frequency Generation Vibrational Spectroscopy Study. J. Am. Chem. Soc. 2010, 132 (37), 13088.

27.  Hung, L. I.; Tsung, C. -K. (Equal Contribution); Huang, W. Y.; Yang, P. D., Room-Temperature Formation of Hollow Cu2O Nanoparticles. Adv. Mater. 2010, 22 (17), 1910.

26.  Huang, W. Y.; Liu, J. H. C.; Alayoglu, P.; Li, Y. M.; Witham, C. A.; Tsung, C. -K.; Toste, F. D.; Somorjai, G. A., Highly Active Heterogeneous Palladium Nanoparticle Catalysts for Homogeneous Electrophilic Reactions in Solution and the Utilization of a Continuous Flow Reactor. J. Am. Chem. Soc. 2010, 132 (47), 16771.

25.  Tsung, C. -K.; Kuhn, J. N.; Huang, W. Y.; Aliaga, C.; Hung, L. I.; Somorjai, G. A.; Yang, P. D., Sub-10 nm Platinum Nanocrystals with Size and Shape Control: Catalytic Study for Ethylene and Pyrrole Hydrogenation. J. Am. Chem. Soc. 2009, 131 (16), 5816.

24.  Kuhn, J. N.; Tsung, C. -K. (Equal Contribution); Huang, W.; Somorjai, G. A., Effect of organic capping layers over monodisperse platinum nanoparticles upon activity for ethylene hydrogenation and carbon monoxide oxidation. J. Catal. 2009, 265 (2), 209.

23.  Joo, S. H.; Park, J. Y.; Tsung, C. -K.; Yamada, Y.; Yang, P. D.; Somorjai, G. A., Thermally stable Pt/mesoporous silica core-shell nanocatalysts for high-temperature reactions. Nat. Mater. 2009, 8 (2), 126.

22.  Huo, Z. Y.; Tsung, C. -K.; Huang, W. Y.; Fardy, M.; Yan, R. X.; Zhang, X. F.; Li, Y. D.; Yang, P. D., Self-Organized Ultrathin Oxide Nanocrystals. Nano Lett. 2009, 9 (3), 1260.

21.  Aliaga, C.; Park, J. Y.; Yamada, Y.; Lee, H. S.; Tsung, C. -K.; Yang, P. D.; Somorjai, G. A., Sum Frequency Generation and Catalytic Reaction Studies of the Removal of Organic Capping Agents from Pt Nanoparticles by UV-Ozone Treatment. J. Phys. Chem. C 2009, 113 (15), 6150.

20.  Tsung, C. -K.; Fan, J.; Zheng, N. F.; Shi, Q. H.; Forman, A. J.; Wang, J. F.; Stucky, G. D., A General Route to Diverse Mesoporous Metal Oxide Submicrospheres with Highly Crystalline Frameworks. Angew. Chem.-Int. Edit. 2008, 47 (45), 8682.

19.  Li, L.; Tsung, C. -K.; Yang, Z.; Stucky, G. D.; Sun, L. D.; Wang, J. F.; Yan, C. H., Rare-earth-doped nanocrystalline Titania microspheres emitting luminescence via energy transfer. Adv. Mater. 2008, 20 (5), 903.

18.  Li, L.; Tsung, C. -K.; Ming, T.; Sun, Z. H.; Ni, W. H.; Shi, Q. H.; Stucky, G. D.; Wang, J. F., Multifunctional Mesostructured Silica Microspheres from an Ultrasonic Aerosol Spray. Adv. Funct. Mater. 2008, 18 (19), 2956. 

17.  Kuhn, J. N.; Huang, W. Y.; Tsung, C. -K.; Zhang, Y. W.; Somorjai, G. A., Structure Sensitivity of Carbon-Nitrogen Ring Opening: Impact of Platinum Particle Size from below 1 to 5 nm upon Pyrrole Hydrogenation Product Selectivity over Monodisperse Platinum Nanoparticles Loaded onto Mesoporous Silica. J. Am. Chem. Soc. 2008, 130 (43), 14026.

16.  Huo, Z. Y.; Tsung, C. -K.; Huang, W. Y.; Zhang, X. F.; Yang, P. D., Sub-two nanometer single crystal Au nanowires. Nano Lett. 2008, 8 (7), 2041.

15.  Huang, W.; Kuhn, J. N.; Tsung, C. -K.; Zhang, Y.; Habas, S. E.; Yang, P.; Somorjai, G. A., Dendrimer templated synthesis of one nanometer Rh and Pt particles supported on mesoporous silica: Catalytic activity for ethylene and pyrrole hydrogenation. Nano Lett. 2008, 8 (7), 2027.

14.  Galusha, J. W.; Tsung, C. -K. (Equal Contribution); Stucky, G. D.; Bartl, M. H., Optimizing sol-gel infiltration and processing methods for the fabrication of high-quality planar Titania inverse opals. Chem. Mat. 2008, 20 (15), 4925.

13.  Fan, J.; Boettcher, S. W.; Tsung, C. -K.; Shi, Q.; Schierhorn, M.; Stucky, G. D., Field-directed and confined molecular assembly of mesostructured materials: Basic principles and new opportunities. Chem. Mat. 2008, 20 (3), 909.

12.  Shi, Q. H.; An, Z. S.; Tsung, C. -K.; Liang, H. J.; Zheng, N. F.; Hawker, C. J.; Stucky, G. D., Ice-templating of core/shell microgel fibers through 'Bricks-and-Mortar' assembly. Adv. Mater. 2007, 19 (24), 4539.

11.  Kou, X. S.; Zhang, S. Z.; Yang, Z.; Tsung, C. -K.; Stucky, G. D.; Sun, L. D.; Wang, J. F.; Yan, C. H., Glutathione- and cysteine-induced transverse overgrowth on gold nanorods. J. Am. Chem. Soc. 2007, 129 (20), 6402.

10.  Kou, X. S.; Zhang, S. Z.; Tsung, C. -K.; Yang, Z.; Yeung, M. H.; Stucky, G. D.; Sun, L. D.; Wang, J. F.; Yan, C. H., One-step synthesis of large-aspect-ratio single-crystalline gold nanorods by using CTPAB and CTBAB surfactants. Chem.-Eur. J. 2007, 13 (10), 2929.

09.   Kou, X. S.; Ni, W. H.; Tsung, C. -K.; Chan, K.; Lin, H. Q.; Stucky, G. D.; Wang, J. F., Growth of gold bipyramids with improved yield and their curvature-directed oxidation. Small 2007, 3 (12), 2103.

08.  Boettcher, S. W.; Fan, J.; Tsung, C. -K.; Shi, Q. H.; Stucky, G. D., Harnessing the sol-gel process for the assembly of non-silicate mesostructured oxide materials. Accounts Chem. Res. 2007, 40 (9), 784.

07.  An, Z. S.; Shi, Q. H.; Tang, W.; Tsung, C. -K.; Hawker, C. J.; Stucky, G. D., Facile RAFT precipitation polymerization for the microwave-assisted synthesis of well-defined, double hydrophilic block copolymers and nanostructured hydrogels. J. Am. Chem. Soc. 2007, 129 (46), 14493.

06.  Tsung, C. -K.; Kou, X. S.; Shi, Q. H.; Zhang, J. P.; Yeung, M. H.; Wang, J. F.; Stucky, G. D., Selective shortening of single-crystalline gold nanorods by mild oxidation. J. Am. Chem. Soc. 2006, 128 (16), 5352.

05.  Tsung, C. -K.; Hong, W. B.; Shi, Q. H.; Kou, X. S.; Yeung, M. H.; Wang, J. F.; Stucky, G. D., Shape- and orientation-controlled gold nanoparticles formed within mesoporous silica nanofibers. Adv. Funct. Mater. 2006, 16 (17), 2225.

04.  Ostomel, T. A.; Shi, Q. H.; Tsung, C. -K.; Liang, H. J.; Stucky, G. D., Spherical bioactive glass with enhanced rates of hydroxyapatite deposition and hemostatic activity. Small 2006, 2 (11), 1261.

03.  Kou, X. S.; Zhang, S. Z.; Tsung, C. -K.; Yeung, M. H.; Shi, Q. H.; Stucky, G. D.; Sun, L. D.; Wang, J. F.; Yan, C. H., Growth of gold nanorods and bipyramids using CTEAB surfactant. J. Phys. Chem. B 2006, 110 (33), 16377.

02.  Wang, J. F.; Tsung, C. -K.; Hayward, R. C.; Wu, Y. Y.; Stucky, G. D., Single-crystal mesoporous silica ribbons. Angew. Chem.-Int. Edit. 2005, 44 (2), 332.

01.  Wang, J. F.; Tsung, C. -K.; Hong, W. B.; Wu, Y. Y.; Tang, J.; Stucky, G. D., Synthesis of mesoporous silica nanofibers with controlled pore architectures. Chem. Mat. 2004, 16 (24), 5169.